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If youre talking about appliances on standby mode, then yes, these can actually use quite a bit of power and cost over time

You'll only go onto the default offer if you don't choose a new plan. You can go to your account on the website and click change energy plan and choose one of the other plans.

Hi, I signed up for Peak Energy Rewards at the beginning of summer and joined a few events. I saved about $25! Great! I'm wondering how frequent are these events over winter? In cold areas where heating is used is it common to see peak events offered on cold days ?

Emissions factors for electricity grids can typically be found on the website of the relevant grid operator or regulatory authority. Some countries also have centralized databases for emissions factors.